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Photo-induced alignment of a photo-crosslinkable liquid-crystalline copolymer film by linearly polarized UV light

โœ Scribed by Nobuhiro Kawatsuki; Chieko Suehiro; Hiroshi Shindo; Tohei Yamamoto; Hiroshi Ono


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
340 KB
Volume
19
Category
Article
ISSN
1022-1336

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โœฆ Synopsis


The anisotropic photoreaction of a liquid-crystalline (LC) copolymer comprising one co-monomer being anisotropically photo-crosslinkable by linearly polarized (LP)-UV light and the other being insensitive to UV-irradiation is presented. Polarized UVand IR studies suggested a photo-induced alignment of the mesogenic side groups during the LP-UV photoreaction at the LC temperature range of the copolymer. The direction of the aligned mesogenic groups is parallel to the electric vector of the incident LP-UV light and the induced birefringence is 0.07.


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