Photo-controlled/living radical polymerization mediated by 2,2,6,6-tetramethylpiperidine-1-oxyl in inert atmospheres
โ Scribed by Yoshida, Eri
- Book ID
- 113039328
- Publisher
- Springer
- Year
- 2012
- Weight
- 174 KB
- Volume
- 290
- Category
- Article
- ISSN
- 0340-255X
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Radical polymerization of 2-, 3-, and 4-chlorostyrenes (ClSts) was investigated with benzoyl peroxide (BPO) as an initiator, in the presence of 4-methoxy-2,2,6,6tetramethylpiperidine-1-oxyl (MTEMPO). The polymerization was performed in bulk for 3.5 h at 95ะC and then continued for a defined time at
Synthesis of poly(styrene-b-tetrahydrofuran (THF)-b-styrene) triblock copolymers was performed by transformation from living cationic into living radical polymerization, using 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (4-hydroxy-TEMPO) as a transforming agent. Sodium 4-oxy-TEMPO, derived from 4