Low fluence (25 mJ.cm Β°2) and high fluence (180 mJ.cm -2) ArF laser (193.3 nm) photolysis of R1C(O)R 2, (R 1, R 2 = CH3, C2H5, C2H3) afford carbon monoxide and hydrocarbons vVnich are in the former case mostly R1-R 2 alkanes and in the latter case R1-R 2 alkanes along with methane, ethene and ethyne
β¦ LIBER β¦
Photo-CIDNP Studies of 2-Butanone and 3-Pentanone in Solution
β Scribed by Vaish, Shiv P.; McAlpine, Robert D.; Cocivera, Michael
- Book ID
- 121336727
- Publisher
- NRC Research Press
- Year
- 1974
- Tongue
- French
- Weight
- 292 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v74-437
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## Abstract A laser flash photolysisβresonance fluorescence technique has been employed to study the kinetics of the reactions of atomic chlorine with acetone (CH~3~C(O)CH~3~; __k__~1~), 2βbutanone (C~2~H~5~C(O)CH~3~; __k__~2~), and 3βpentanone (C~2~H~5~C(O)C~2~H~5~; __k__~3~) as a function of temp