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Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate

✍ Scribed by Xianming LI; Yunjie DING; Guiping JIAO; Jingwei LI; Li YAN; Hejun ZHU

Book ID
104452869
Publisher
Elsevier Science
Year
2008
Weight
295 KB
Volume
29
Category
Article
ISSN
1872-2067

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The influence of the cationic promoters (M = Li, Na, K, Rb, Cs) on silica-supported rhodium catalysts was examined in the hydroformylation of propene at 413 K and atmospheric pressure. The catalysts were prepared by aqueous co-impregnation of RhCl 3 •3H 2 O and alkali-metal chloride. The rhodium to