Phosphorus Compounds. III. Pyrolysis of Tertiary Phosphine Oxides 1-3
โ Scribed by Bailey, William J.; Muir, William M.; Marktscheffel, Fritz
- Book ID
- 118193656
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 633 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
4. (CH,CHOHCH,),P=O ( I V ) . From 11.1 g (0.0404 mole) 111, 50 ml H,O, 6.3 g (0.089 mole) chlorine, pH kept a t 4-7; procedure and isolation as in 2 gives 8.5 g (93.6%) of IV, a colorless viscous liquid, 31P-chem. shift (in H,O) -51.0 ppm: lH-NMR. (in D,O) : a) at 1.8 ppm ( J H H 6, JPCH 1.4Hz, 9H)
state is again in accordance with the idea that ring closure to a diaziridine is favoured in the first excited state as also indicated by the PPP calculation. This work is part of project No. SR 2.120.69 of the Schweizerischer Nationalfonds. Financial support by CIl3A-GEIGY A G and a generous gift
## Abstract For Abstract see ChemInform Abstract in Full Text.
Upon treatment with LDA or alkyllithium, enantiomers of P-chiral phosphinates, phosphinothioates, phosphinoamidates, thionophosphinates, thionophosphinothioates and thionophosphinoamidates undergo clean [1,3]-and [1,2]-rearrangements with complete stereoselectivity, with retention of configuration a