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Phosphorus-31 Solid-State NMR Study of Iminophosphines: Influence of Electronic Structure and Configuration of the Double Bond on Phosphorus Shielding

✍ Scribed by Gudat, D.; Hoffbauer, W.; Niecke, E.; Schoeller, W. W.; Fleischer, U.; Kutzelnigg, W.


Book ID
120569514
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
973 KB
Volume
116
Category
Article
ISSN
0002-7863

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The 15N NMR spectra of a series of bis(imino)phosphoranes X-P(=NR)=NR" [X = tBu, NHtBu, OMes\*, P(tBu,), StBu (2a-e)], Br-P(=NMes\*) (2f) and Mes\*(Me,Si)N-P(=NtBu)=NSiMe, (2g) were measured and assigned using a combination of 'H-and ,'P-based INEPT techniques. The data reveal a close correlation be