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Phosphonium salts [Ph3AlkP]2+[Hg2I6]2−and [Ph3AlkP]2+[Hg4I10]2−: Synthesis and structure

✍ Scribed by V. V. Sharutin; V. S. Senchurin; N. N. Klepikov; O. K. Sharutina


Book ID
110182190
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
248 KB
Volume
54
Category
Article
ISSN
0036-0236

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Synthesis and Crystal Structure of Hg3S2
✍ Johannes Beck; Sylvia Hedderich 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 207 KB

The reactions of HgS and HgSe with HgI 2 yield Hg 3 S 2 I 2 and Hg 3 Se 2 I 2 , respectively. Orange crystals of Hg 3 S 2 I 2 and light red crystals of Hg 3 Se 2 I 2 are formed in evacuated glass ampoules at 2603C in yields of 50% as the only crystalline compounds. The crystal structures have been s