Phosphonium Salt Formation of the Second Kind
β Scribed by Priv.-Doz. Dr. H. Hoffmann; Dipl.-Chem. H. J. Diehr
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 895 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
Organic corripounds containing a positively polarized halggen uiom react with tertiary phosphincs either with reductive elimination of the halogen or with formation of phosphoniuni salts and quasi-phosphoniiini salts, depending on the solvent. In this reaction, the phosphiire first attacks the halogen. ~ 3. From amides and esters of cc-halogenocarboxylic acids a-halogenoalkylphosphine oxides 4. From cc$-dihalogenocarbonyl compounds.
π SIMILAR VOLUMES
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metric electric field produced at the halide nucleus by the metal ion. Rates of reactions such as Cd(H,0)62' + Br-+ Cd(H,O),Brr + H,O can be evaluated. [?5]