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Phosphonate Aldehyde Annulation − A One-Pot Synthesis of Hydroxycycloalkenoic Esters − Application to Analogs of Glycinoeclepin A

✍ Scribed by George A. Kraus; Prabir K. Choudhury

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
104 KB
Volume
2004
Category
Article
ISSN
1434-193X

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Phosphonate compounds mimic the first transition state from a C-4 chiral synthon, 3-buten-1,2-diol -and treated with n-pentylphosphonic dichloride and p-nitrophenol to occurring during enzymatic carboxyester hydrolysis of natural substrates by forming a covalent bond with the afford the correspondin