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Phosphoglucoisomerase-catalyzed interconversion of hexose phosphates; diastereotopic specificity, isotopic discrimination and intramolecular hydrogen transfer

โœ Scribed by Veronique Liemans; Francine Malaisse-Lagae; Rudolph Willem; Willy J. Malaisse


Book ID
113267482
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
945 KB
Volume
998
Category
Article
ISSN
0167-4838

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The discrimination between the isotopes of hydrogen in the reaction catalyzed by yeast phosphoglucoisomerase is examined by NMR, as well as by spectrofluorometric or radioisotopic methods. The monodirectional conversion of D-glucose 6-phosphate to D-fructose 6-phosphate displays a lower maximal velo