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Phosphine σ-sydnonyl complexes of Ni, Pd, and Pt

✍ Scribed by V. N. Kalinin; F. M. She; V. N. Khandozhko; P. V. Petrovskii


Book ID
110300183
Publisher
Springer
Year
2001
Tongue
English
Weight
267 KB
Volume
50
Category
Article
ISSN
1573-9171

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σ-Acetylides of Ni(II), Pd(II), and Pt(I
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Several stable alkynyl complexes K2 [M(CYR)4] [M = Ni(H), Pd(II), PtfII); R = -CH,-C(Ph),(CN), -CH2-C(CH3J2(CN)] have been obtained. The IR spectra of these complexes have been studied and an attempt to assign v(M-C) stretching frequencies has been made. Study of the thermal decomposition by thermal

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Heterobimetallic complexes of the types [Cp2Ti(#-EAr)2-M(dppe)](C104) 2 [( 1)-( 4); M, E= Ni, Te (I); Ni, Se (2); Pt, Te (3); Pt, Se (4); Ar = Ph (a), C6H~-4-Me (b), C6H4-4-OMe (e), C6H4-4-OEt (d)] and [Cp2Ti(/~-TeAr)z-MC12] [M=Pd (5), Pt (6)] were obtained by the reactions of Cp2Yi(EAr) 2 with M(dp