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Phosphine ligands for the construction of polynuclear complexes. I. Bis(diphenylphosphinomethyl)phenylphosphine complexes of palladium(II) and rhodium(I)

✍ Scribed by Guimerans, Rosalvina R.; Olmstead, Marilyn M.; Balch, Alan L.


Book ID
127218728
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
392 KB
Volume
105
Category
Article
ISSN
0002-7863

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The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi