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Phosphine-Catalyzed Synthesis of 1,3-Dioxan-4-ylidenes.

✍ Scribed by Xue-Feng Zhu; Christopher E. Henry; Jay Wang; Travis Dudding; Ohyun Kwon


Publisher
John Wiley and Sons
Year
2005
Weight
39 KB
Volume
36
Category
Article
ISSN
0931-7597

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Conformational Analysis of oligo-1,3-Dio
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Whereas simple 4,4Ј-bi(1,3-dioxanyl)s 16 and 19 displayed little conformational preference at the inter-ring bond, their derivatives 4 and 13, with equatorial methyl groups in the 5and 5Ј-positions, each showed a strong conformational preference to populate a conformation with a gauche arrangement o