𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Phosphazene-catalyzed ring-opening polymerization of ε-caprolactone: influence of solvents and initiators

✍ Scribed by Alamri, Haleema; Zhao, Junpeng; Pahovnik, David; Hadjichristidis, Nikos

Book ID
126654154
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
732 KB
Volume
5
Category
Article
ISSN
1759-9954

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Lanthanide Thiolate Complexes: Novel Ini
Lanthanide Thiolate Complexes: Novel Initiators for Ring-opening Polymerization of ε-Caprolactone
✍ Hong-Mei Sun; Huan-Rong Li; Chang-Sheng Yao; Ying-Ming Yao; Hong-Ting Sheng; Qi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini

Influence of Microwave Irradiation on th
Influence of Microwave Irradiation on the Lipase-Catalyzed Ring-Opening Polymerization of ε-Caprolactone
✍ Patrick Kerep; Helmut Ritter 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 97 KB

## Abstract **Summary:** The microwave (MW)‐assisted lipase‐catalyzed ring‐opening polymerization of __ε__‐caprolactone in boiling solvents was investigated for the first time. In case of boiling toluene or benzene the MW‐assisted reaction proceeded significantly slower compared to oil bath heating