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PhINSes: A New Iminoiodinane Reagent for the Copper-Catalyzed Aziridination of Olefins

✍ Scribed by Dauban, Philippe; Dodd, Robert H.

Book ID
118737814
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
112 KB
Volume
64
Category
Article
ISSN
0022-3263

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Preparation and evaluation of nitrene pr
Preparation and evaluation of nitrene precursors (PhI=NSO2Ar) for the copper-catalyzed aziridination of olefins
✍ Mikael J. SΓΆdergren; Diego A. Alonso; Ashutosh V. Bedekar; Pher G. Andersson πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 212 KB

The preparation of different lN-(arenesulfonyl)iminolphenyliodinanes is described along with an evaluation of their utility as nitrene precursors for the copper-catalyzed aziridination of different olefins. The best results were obtained with p-NO2-Cr, H, flO~=IPh and p-MeO-Ce~I4SO2N=IPh, both of wh