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Pheromone Synthesis, LXXXI1) New Synthesis of the Enantiomers of exo-Brevicomin, the Pheromone of Dendroctonus brevicomis Le Conte

✍ Scribed by Mori, Kenji ;Seu, Young-Bae


Book ID
102365489
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
336 KB
Volume
1986
Category
Article
ISSN
0947-3440

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✦ Synopsis


A new sysnthesis of the title compounds (lR,5S,7R)-l and (IS,5R,7S)-l from the enantiomers of tartaric acid is described.

Pheromonsynthesen, LXXXI '). -Neue Synthese der Enantiomeren von em-Brevicomin, dem Pheromon von Dendroctonus bvcvicomis Le Conte

Eine neue Synthese der Titelverbindungen (IR,5S,7R)-l und (lS,5R,7S)-l aus den Enantiomeren der Weinsaure wird beschrieben.


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## Abstract The enantiomers of grandisol (1) and lineatin (2) have been synthesized by resolving the key (Β±)‐hydroxy ether (Β±)‐7 as its diastereomeric esters 8 and 8β€² with (βˆ’)‐camphanic acid.