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Pheromone Synthesis, CXXXVII. A New Synthesis of (+)-Grandisol

✍ Scribed by Mori, Kenji ;Fukamatsu, Kunio

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 521 KB
Volume: 1992
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199219920187

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✦ Synopsis

Abstract

The natural and (+)‐enantiomer of grandisol [1, (1__R__,2__S__)‐(+)‐2‐isopropenyl‐1‐methylcyclobutaneethanol] has been synthesized from (R)‐(—)‐carvone (2) by employing the intramolecular alkylation of 8 to give 9 as the key step.

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