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Pheromone Synthesis, CXVI Conversion of the Enantiomers of Sulcatol to the Enantiomers ofcis-Pityol, a Volatile Compound from the Elm Bark BeetlePteleobius vittatus

โœ Scribed by Mori, Kenji ;Puapoomchareon, Prapai


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
191 KB
Volume
1989
Category
Article
ISSN
0947-3440

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Pheromone synthesis, CVI. Synthesis of a
โœ Mori, Kenji ;Puapoomchareon, Prapai ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 311 KB

Oxymcrcuration of (R)-sulcatol (1) to (3R,6R)-2 was followed by its treatment with NaBH, and oxygen lo give (3S,6R)-tetra-Iiydro-2,2,6-trimethyl-2H-pyran-3-01 ( 3 4 and (3R,6R)-3n'. In thc same manner, (3R.69-3a and (3S,GS)-3a' were synthesized from ( Q I . Tetrahydro-2,2,6-trimethyl-2H-pyran-3-01