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Pheromone Synthesis, CXLIII. Synthesis and Absolute Configuration of the Hemiacetal Pheromone of the Spined Citrus BugBiprorulus bibax

✍ Scribed by Mori, Kenji ;Amaike, Masayasu ;Oliver, James E.

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
580 KB
Volume
1992
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

(3__S__,4__R__,1′E)‐3,4‐Bis(1′‐butenyl) tetrahydro‐2‐furanol (1) was synthesized from 1,3‐butadiene and maleic anhydride by employing the HLADH‐catalyzed enzymatic oxidation of meso‐diol 2 as the key step, and shown to be identical with the pheromone produced by the dorsal abdominal glands of the male spined citrus bug (Biprorulus bibax).

📜 SIMILAR VOLUMES

Pheromone Synthesis, CLVIII. New Synthes
Pheromone Synthesis, CLVIII. New Synthesis and Revision of the Absolute Configuration of the Hemiacetal Pheromone of the Spined Citrus BugBiprorulus bibax
✍ Mori, Kenji ;Amaike, Masayasu ;Watanabe, Hidenori 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 901 KB

## Abstract The enantiomers and the racemate of (3__R__,4__S__,1′__E__)‐3,4‐bis(1′‐butenyl)tetrahydro‐2‐furanol (1) were synthesized by employing Ireland's ester enolate Claisen rearrangement of 5 as the key reaction to provide the corresponding lactone 3 via 4. Optically active 3 was prepared by e

Pheromone synthesis CLXIX. Improved synt
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## Abstract The racemate of (3__R__,4__S__,1′__E__)‐3,4‐bis(1′‐butenyl)tetrahydro‐2‐furanol (1) was synthesized by employing Ireland's ester enolate Claisen rearrangement of (±)‐5 as the key step. The synthesis was efficient enough to provide 23.7 g of (±)‐1 in 41% overall yield based on (±)‐7 (8 s

Pheromone Synthesis, CLXXXIV. Synthesis
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✍ Nakayama, T??Ru ;Mori, Kenji 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 666 KB

## Abstract The racemate as well as both the enantiomers of sordidin (1‐ethyl‐3,5,7‐trimethyl‐2,8‐dioxabicyclo[3.2.1])octane were synthesized, and the natural pheromone was shown to be (1__S__,3__R__,5__R__,7__S__)‐(+)‐1.

ChemInform Abstract: Pheromone Synthesis
ChemInform Abstract: Pheromone Synthesis. Part 184. Synthesis and Absolute Configuration of Sordidin, the Male-Produced Aggregation Pheromone of the Banana Weevil, Cosmopolites sordidus.
✍ T. NAKAYAMA; K. MORI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v