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Pheromone synthesis, CLX. A new synthesis of the oviposition-deterring pheromone of the European cherry fruit flyRhagoletis cerasi L.

✍ Scribed by Mori, Kenji ;Qian, Zhao-Hui

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
559 KB
Volume
1994
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

A new synthesis of the ammonium salt 1c of (8__RS__,15__R__)‐N‐[(β‐D‐glucopyranosyloxy)‐8‐hydroxypalmitoyl]taurine, the oviposition‐deterring pheromone of the European cherry fruit fly Rhagoletis cerasi L., was achieved by starting from 2,3,4,6‐tetra‐O‐pivaloyl‐α‐D‐glucopyranosyl bromide (2), taurine (4), ethyl (R)‐3‐hydroxybutanoate (5), propargyl alcohol (6), methyl acetoacetate (7), and 1,6‐hexanediol (8). magnified image

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