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Phenyl/Pentafluorophenyl Interactions and the Generation of Ordered Mixed Crystals: sym-Triphenethynylbenzene and sym-Tris(perfluorophenethynyl)benzene

✍ Scribed by Francesco Ponzini; Ralph Zagha; Kenneth Hardcastle; Jay S. Siegel


Book ID
101371063
Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
108 KB
Volume
39
Category
Article
ISSN
0044-8249

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Phenyl/Pentafluorophenyl Interactions an
✍ Francesco Ponzini; Ralph Zagha; Kenneth Hardcastle; Jay S. Siegel 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

Although benzene and perfluorobenzene adopt crystal structures with ªherringboneº (T-shaped) pairwise orientations, combination of the two liquids produces an intimate 1:1 solid complex in which the basic short range order is a face-to-face stack. The driving force for this specific mixing stems f