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Phenyliodine(III)-Bis(trifluoroacetate)-Mediated Olefin Amidohydroxylation Reaction.

✍ Scribed by Imanol Tellitu; Andrea Urrejola; Sonia Serna; Isabel Moreno; M. Teresa Herrero; Esther Dominguez; Raul SanMartin; Arkaitz Correa

Book ID
102002720
Publisher
John Wiley and Sons
Year
2007
Weight
36 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract When appropriately substituted amides are treated with PIFA in a non‐nucleophilic solvent like trifluoroethanol, a stable __N__‐acylnitrenium ion is generated. If under such conditions a C=C double bond is present in the molecule, an intramolecular cyclization process takes place in an

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.