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Phenylcarbene from 3,5-diphenyl-1-pyrazoline

✍ Scribed by Buchwalter, S. L.; Closs, G. L.

Book ID: 127391591
Publisher: American Chemical Society
Year: 1975
Tongue: English
Weight: 407 KB
Volume: 40
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00905a036

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trans -3,5-DIPHENYL-1-PYRAZOLINE

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Decomposition of 3,5-Diphenyl-1-pyrazoline. A Correction

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The title compound, C 21 H 17 FN 2 , was prepared from phenylhydrazine and 1-phenyl-3-(p-fluorophenyl)-2-propenyl-1ketone. The pyrazolinyl ring forms dihedral angles of 11.87 (12), 8.30 (12) and 65.89 (12) with phenyl rings at the 1 and 3 positions and the fluorophenyl ring, respectively.

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Two N-Substituted 3,5-Diphenyl-2-pyrazoline-1-thiocarboxamides.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

3-(4-Fluorophenyl)-1,5-diphenyl-2-pyra

3-(4-Fluorophenyl)-1,5-diphenyl-2-pyrazoline

✍ Guo, Huan-Mei ;Jian, Fang-Fang ;Zhou, Li-You ;Zhao, Pu-Su ;Zheng, Jian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 195 KB

The title compound, C 21 H 17 FN 2 , crystallizes with two independent molecules in the asymmetric unit. The pyrazoline and 4-fluorophenyl rings are planar. The phenyl ring at the 5position and the pyrazoline heterocycle are almost perpendicular.