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Phenoxyl-copper(II) complexes: models for the active site of galactose oxidase

✍ Scribed by Sokolowski, Achim; Leutbecher, Heiko; Weyhermüller, Thomas; Schnepf, Robert; Bothe, Eberhard; Bill, Eckhard; Hildebrandt, Peter; Wieghardt, K.


Book ID
113052823
Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
466 KB
Volume
2
Category
Article
ISSN
1432-1327

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A Structural Model for the Galactose Oxi
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Galactose oxidase (GO) contains one copper ion at its active site and performs a two-electron oxidation of primary alcohols to aldehydes, coupled with a reduction of O 2 to eomer in 68 % yield. The entire sequence was performed in 24 linear steps from (S)-malic acid. The material thus obtained was s