𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Phenomenology related to the kinetics of Kolbe electrosynthesis

✍ Scribed by R.M. Cerviño; W.E. Triaca; A.J. Arvía

Book ID
103175146
Publisher
Elsevier Science
Year
1984
Weight
535 KB
Volume
172
Category
Article
ISSN
0022-0728

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Mechanism of the Kolbe electrosynthesis
Mechanism of the Kolbe electrosynthesis
✍ L. Eberson 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 508 KB

Ah&act-A mechanism proposed by Conway and Vijh for the Kolbe reaction is criticized, and the author's previously given mechanism is defended, on the general ground that the adsorbed intermediates postulated by Conway and Vijh could not give the known products because of stereochemical considerations

An energetic explanation of the kolbe el
An energetic explanation of the kolbe electrosynthesis
✍ K. Sasaki; K. Uneyama; S. Nagaura 📂 Article 📅 1966 🏛 Elsevier Science 🌐 English ⚖ 318 KB

The product distribution of the Kolbe electrolysis, which varies with the kind of carboxylic acid electrolysed, has been considered from the thermochemical standpoint. Approximating the bond dissociation energy of the carboxylic hydrogen, D(RCOO-II), to be 115 Kcal/mol, the heat of reaction for vari