Phenomenology of solvent matrix spectroscopic effects

✍ Scribed by Barry Dellinger; Michael Kasha

• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 585 KB
• Volume: 38
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(76)80244-8

✦ Synopsis

Rigid

-matris perturbations are applied to various molecular potcnti3ls in acccrdancc with tile l3orn--Oppcn!~eimcr appreach dcvcloped in an earlier paper. The potentials considered xc the (a) Morse vibrational, (b) repulsive, (c) double-bond torsional, (d) double-minimum. and (e) pseudo-lahn-Teller.

Predictions are made concerning the novel phcnomcnology cxpectcd for each matris-perturbed potential.