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Phenomenological description of the transport of isotopes in electrolytic systems

✍ Scribed by H. Schönert

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
564 KB
Volume
27
Category
Article
ISSN
0013-4686

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✦ Synopsis

The equations ofirreversible thermodynamics are applied to the isothermal-isobaric transport of isotopes in multicompunent electrolytic systems. The resulting flux-force relations can he written entirely in terms of conventional transport coefficients: transference numbers, electrical conductivity, diffusion coefficients of electroneutcal electrolytes and intra-dimusion coefficients. Some applications are discussed.

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✍ V.M. Zhdanov; G.A. Tirskiy 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 440 KB

Different forms of expressing diffusion and heat fluxes in multicomponent mixtures, obtained by methods of non-equilibrium thermodynamics and the kinetic theory of gas mixtures, are analysed and compared. It is shown that an alternative representation of the linear relations of non-equilibrium therm