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Phenol solvation and states of aggregation of tetraethylammonium halides in carbon tetrachloride. Far and mid infrared study

✍ Scribed by P. Bacelon; J. Corset; C. de Loze

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 489 KB
Volume: 32
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85214-6

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✦ Synopsis

The sp&of mixtures of tetiaal~iammonium halides and phenol in carbon tetrachloride have been compared in the ', mid and far infrared regjons. The saltc, exist in CC&in large aggxegates which are dissociated by phenol into ion pairs hy-:

., drogci borided tu'phenol and multisolvated anions.

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Far-infrared absorption in liquid carbon tetrachloride: A theoretical study of the lineshape and intensity

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Liquid carbon tetrachloride displays a far-infrared absorption spectrum which is primarily the result of collisional processes involving octapolar and bexadecapolar induction of dipole moments. These moments are modulated by both the rotational and translational motions of the CC4 molecules. The rot