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Phenol oxidative coupling in the biogenesis of the macrocyclic spermine alkaloids aphelandrine and orantine inAphelandrasp.

✍ Scribed by Lenka Nezbedová; Manfred Hesse; Konstantin Drandarov; Laurent Bigler; Christa Werner


Book ID
106114492
Publisher
Springer-Verlag
Year
2001
Tongue
English
Weight
160 KB
Volume
213
Category
Article
ISSN
0032-0935

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New reagent for oxidative phenol couplin
✍ Lenka Nezbedová; Manfred Hesse; Konstantin Drandarov; Christa Werner 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 74 KB

The soluble protein fraction of barley seedlings (Hordeum vulgare, Gramineae) in the presence of O 2 stereoselectively catalyzes the intramolecular phenol coupling of the monocyclic spermine base (S)-dihydroxyverbacine to the bicyclic aphelandrine in preparative yield. The expected microsomal-bond c