Phenacyldimethylsulfonium ylide-mercuric chloride complex initiated radical polymerization of 4-vinyl pyridine

Kinetics and mechanism of the radical co

Kinetics and mechanism of the radical copolymerization of 4-vinyl pyridine with methyl acrylate initiated by p-acetylbenzylidene triphenylarsonium ylide

✍ S. P. Tiwari; C. L. Gehlot 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

## Abstract The free‐radical copolymerization of 4‐vinyl pyridine (4‐VP) with methyl acrylate (MA) initiated by __p__‐acetylbenzylidene triphenylarsonium ylide at 60 ± 0.1°C with dioxane as an inert solvent yielded random copolymers. The kinetic equation was __R__~__p__~ ∝ [Ylide]^0.83^[4‐VP]^0.33^