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Phase transitions in Pb8O5(XO4)2 (X = As and V) compounds

✍ Scribed by E. A. Oliveira; E. N. Silva; A. R. Paschoal; S. M. Dantas; I. Guedes; J. Mendes-Filho; G. Polla; A. P. Ayala

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 488 KB
Volume: 42
Category: Article
ISSN: 0377-0486
DOI: 10.1002/jrs.2886

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A new compound, Bi 3.5 V 1.2 O 8.25 (25.53 mol% V 2 O 5 ), has been found in the system Bi 2 O 3 +V 2 O 5 . It crystallizes in the triclinic symmetry with a ‫؍‬ 16.452(1) A > , b ‫؍‬ 16.886(1) A > , c ‫؍‬ 7.0914(7) A > , ‫؍‬ 91.330(8)3, ‫؍‬ 95.186(9)3, ‫؍‬ 96.031(9)3, and Z ‫؍‬ 10. The structure is