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Phase transitions in one-dimensional cluster-interaction fluids II. Simple logarithmic model

✍ Scribed by B.U Felderhof; Michael E Fisher

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 561 KB
Volume: 58
Category: Article
ISSN: 0003-4916
DOI: 10.1016/0003-4916(70)90245-9

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✦ Synopsis

The one-dimensional many-body cluster interaction models studied in Part I are here specialized to the case where the many-body potentials, when they act, are constants independent of the particle coordinates. The nature and location of the phase transition which arises when the surface energy W(I) varies as In 1 is studied. The behavior of various thermodynamic properties along and near the vapor pressure curve, p,(T), is investigated in detail. It is shown that critical-like phenomena occur all along the vapor pressure curve; specifically, p -p. varies as (v -zQrn as the specific "volume" v approaches the gaseous side of the coexistence curve at constant T, with S(T) > 1 depending on TIT,.

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