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Phase transitions in new BEDT-TTF κ-phase salts with hexacyanometalate anions [M(CN)63− M=Co(III) and Fe(III)]

✍ Scribed by Pierre Le Maguerè; Lahcène Ouahab; Nathalie Corian; Carlos J. Gómez-García; Pierre Delhaès; Jacky Even; Marcel Bertault

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 458 KB
Volume: 97
Category: Article
ISSN: 0038-1098
DOI: 10.1016/0038-1098(95)00598-6

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Infrared spectra of β-Phase BEDT-TTF sal

Infrared spectra of β-Phase BEDT-TTF salts with hexacyanometalate anions (M(CN)3−6; M ≡ CoIII, FeIII, CrIII)

✍ R. Świetlik; P. Le Maguerès; L. Ouahab 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 445 KB

The structure of the Fe salt is triclinic (a = 9.391( ), b = 12.730(3), c = 19.148(3) A; α = 104.11(2)°, β = 92.60(2)°, γ = 98.64(2)°; space group PT 1, Z = 1). 2 The BEDT-TTF molecules are arranged in pentamerised stacks with the sequence … BACAB …