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Phase transitions and ionic conductivity in Bi4V2O11 an oxide with a layered structure

โœ Scribed by F. Abraham; M.F. Debreuille-Gresse; G. Mairesse; G. Nowogrocki

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
125 KB
Volume
28-30
Category
Article
ISSN
0167-2738

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โœฆ Synopsis

The s~cture .f ~i.V~, I ~asist s ~f ~i20~ laye~ inler]=v~ with V~O, ,h~. Dfffr th~al aa~]~,~s sho~a tn~e reve~blr pha~ Iran,ilion~ at 720. 840 ~nd t 150 ~ The cells of the low I~peraturr fo~s derive from the high lem~t a~ tetmg~al cell ~dumi~ty alr these Imnsiti~s and reveal t~ fuaher on~ al 920 and 975 K The condu~ livily is in the ~nge 0.0O1-0.01 (~ era) -' for lhe a pha~ ~nd 0.i-I (~cm) -I forlhe~Ohase~emebi~sp~ie~a~pmbably

๐Ÿ“œ SIMILAR VOLUMES

Preparation, characterization and oxide
Preparation, characterization and oxide ion conductivity in U-substituted Bi4V2O11
โœ O. Thery; R.N. Vannier; C. Dion; F. Abraham ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 541 KB

A Bi2V,-,-vUxBiy05.~+0.5x-y solid solution derived from Bi,V,O, , has been prepared and characterized with x up to 0.125 for y = b. Partial substitution of Uhf for V" in Bi,V,O, , leads to the stabilization at room temperature of the high-oxide ion conducting y-phase, in contrast with other M6+ dopa

Synthesis and Crystal Structure of a New
Synthesis and Crystal Structure of a New Mixed Orthovanadate-Pyrovanadate Series: MBa2V3O11 or MBa2V2PO11 with M = Bi, In, or a Rare Earth
โœ Jinfan Huang; Qiuyi Gu; Arthur W. Sleight ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 435 KB

A new series of vanadates with the general formula \(M \mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{O}_{11}\), where \(M\) may be \(B i\), In, or a rare earth, has been synthesized and structurally characterized by single crystal X-ray diffraction and powder X-ray diffraction. The general formula may be