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Phase transition sequence in ferroelectric Aurivillius compounds investigated by single crystal X-ray diffraction

✍ Scribed by Boullay, P.; Tellier, J.; Mercurio, D.; Manier, M.; Zuñiga, F.J.; Perez-Mato, J.M.

Book ID: 118045821
Publisher: Elsevier Science
Year: 2012
Tongue: English
Weight: 746 KB
Volume: 14
Category: Article
ISSN: 1293-2558
DOI: 10.1016/j.solidstatesciences.2012.07.014

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Four phase transitions at: T h C1 ¼ 267:1 K, T h C2 ¼ 258:8 K, T h C3 ¼ 254:1 K and T h C4 ¼ 195:4 K (on heating) and at T c C1 ¼ 263:8 K, T c C2 ¼ 255:4 K, T c C3 ¼ 246:0 K (on cooling) were determined for [Ca(H 2 O) 4 ](ClO 4 ) 2 between 90 and 295 K by means of differential scanning calorimetry