Phase transition of the BEDT-TTF charge-transfer complex with ClO4
β Scribed by Mototada Kobayashi; Toshiaki Enoki; Kenichi Imaeda; Hiroo Inokuchi; Gunzi Saito
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 172 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0378-4363
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym β«Ψβ¬ 2,2-bipyrimidine. The Fe salt,
The dimer approach was proposed for the normal coordinate analysis of BEDT-TTF+ molecular vibrations. It was shown that, within the framework of the approximation used, the appearance of additional bands in the IR as well as in Raman spectra may be explained as due to the reduction of symmetry of th