The interracial micellization of a homologous series of N-alkyl pyrimidinium salts and their transformations on a Hg electrode are studied by means of differential capacitance measurements. It is shown that below the crnc a monolayer film of surface micelles is formed at positive polarizations, arou
Phase transformations at the Hg/aqueous solution interface in the presence of cetyltrimethylammonium cations
β Scribed by A. Pappa-Louisi; P. Nikitas; Ph. Andonoglou
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 925 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The adsorption of N-tosylglycine (CH,+-SO,-NH-CH,COOH) has been studied at the mercury/aqueous solution interface (0.1 M NaClO, as base electrolyte) with the aim of comparing the interfacial properties of the molecular forms of the amino acid present in solution at different pH values. The analysis
Abetrsct-The differential capacity characteristics of an electrified Hg/O.l N Na,SO, aqueous solution interface is studied in the presence of methylpyridines. It is shown that the adsorbed films of 2-and 3-methylpyridines undergo a phase transformation at potentials around -l.OV (see) and at concent
The formation and properties of mixed miceilar-like films on the Hg electrode in the presence of two surfactants in the electrolyte solution is studied by means of differential capacity measurements. The experimental data are analysed on the basis of previous theoretical treatments. It is found that