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Phase Transfer Catalyzed Reactions of Chloroform with Methacrylic Esters.

✍ Scribed by M. Fedorynski; A. Blazejczyk; M. Makosza

Publisher
John Wiley and Sons
Year
2003
Weight
83 KB
Volume
34
Category
Article
ISSN
0931-7597

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ReactIon of chloroform wth ketone enol esters Id,e carried out in the presence of 50% aq NaOH and benzyltrlethylammomum chloride (TEBAC) as a catalyst gives ,qem-dnzhlorocyclopropanes 3d,e In the case of enol esters of aldehydes, adducts of trlchloromethyl anion 2a,b,f,b (from la,b,f,h) or mixtures