Phase Transfer Catalyst-Induced Free Radical Polymerization of Acrylonitrile Using Water Soluble Initiator – A Kinetic Study
✍ Scribed by Yoganand, K. S.; Vidhya, K. R.; Umapathy, M. J.
- Book ID
- 121333168
- Publisher
- Taylor and Francis Group
- Year
- 2009
- Tongue
- English
- Weight
- 571 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0091-4037
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This article presents the systematic study of kinetics and mechanism of phase-transfer-catalyzed free-radical polymerization of acrylonitrile (AN) and watersoluble initiator potassium peroxomonosulphate (PMS) coupled with tetrabutyl phosphonium chloride (TBPC) in ethyl acetate/water biphase system i
## Abstract In this article, the kinetics and mechanism of the free‐radical polymerization of acrylonitrile (AN) using potassium peroxydisulfate (PDS) as a water‐soluble initiator in the presence of synthesized 1,4‐bis(triethyl methyl ammonium) benzene dichloride (DC‐X) as a phase‐transfer catalyst