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Phase Transfer Catalysis in Solid—Liquid System as a Selective Method of Mono-alkylation of α-Sulfonyl Thioesters.

✍ Scribed by Blanka Wladislaw; Liliana Marzorati; Regina M. A. Neves; Claudio Di Vitta

Publisher
John Wiley and Sons
Year
2002
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Hung-Ming Yang; Ch'un-Min Wu; Huai-En Wu 📂 Article 📅 2000 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 117 KB 👁 2 views

The kinetics of phase-transfer catalyzed etheri®cation of sodium phenoxide with ethyl 2-bromoisobutyrate to produce ethyl 2-phenoxyisobutyrate in a solid±liquid system has been investigated. Being catalyzed by the quaternary `onium salts, the reaction was carried out in a stirred batch reactor to ex