Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of p-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc) 2 /PPh 3 as the c
โฆ LIBER โฆ
Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes
โ Scribed by Hashimoto, Takuya; Sakata, Kazuki; Tamakuni, Fumiko; Dutton, Mark J.; Maruoka, Keiji
- Book ID
- 118742966
- Publisher
- Nature Publishing Group
- Year
- 2013
- Tongue
- English
- Weight
- 539 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1755-4330
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A study into the enantioselecfive epoxidation of a, [3-unsatma~ ketones utilising Cinchona alkaloidderived q,m\_~nmT -mmonium ~-Wansfer catalysts beating m N-an~racenylmethyl function is presented. It has been found that the O-benzyl derivatives of these catalysts in conjunction with sodium hypcchlo