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Phase stability limits and solid-state decomposition of Bi2Sr2CaCu2O8+δ and Bi2Sr2Ca2Cu3O10+δ in reduced oxygen pressures

✍ Scribed by L.M. Rubin; T.P. Orlando; J.B. Vander Sande; G. Gorman; R. Savoy; R. Swope; R. Beyers

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
522 KB
Volume
217
Category
Article
ISSN
0921-4534

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✍ Weimin Bian; Yimei Zhu; Y.L. Wang; M. Suenaga 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 490 KB

We report our observations on and identification of an intermediate phase, (Bi,Pb)4Sr4CaaCusOls+8 (denoted as Bi/4435), during the phase transformation of (Bi,Pb)2Sr2CaCu2Os+ 8 (Bi/2212) to (Bi,Pb)2Sr2Ca2Cu3010 + 8 (Bi/2223) in powder-in-tube processed tapes. The unit cell of the phase consists of o