Phase separation of poly(N-isopropylacrylamide) in water: a spectroscopic study of a polymer tagged with a fluorescent dye and a spin label
✍ Scribed by Winnik, Francoise M.; Ottaviani, M. Francesca; Bossman, Stefan H.; Pan, Wenseng; Garcia-Garibay, M.; Turro, Nicholas J.
- Book ID
- 125429273
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 990 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0022-3654
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Polystyrene (PS) samples carrying terminal or in-chain nitroxide spin labels have been blended with poly(vinyl methyl ether) (PVME) in varying proportions and their electron spin resonance (ESR) spectra recorded over a range of temperatures. The spectra are mainly of the slow-motion type but reÑect
## Abstract __N__‐isopropylacrylamide and __N__‐acryloxysuccinimide have been copolymerized in various mixtures of terrahydrofuran and toluene using azobisisobutyronitrile as initiator. Polymerization has been conducted for 24 h at 50°C under a slightly positive pressure of nitrogen. The copolymers