## Abstract Microphase separation in solutions of weakly charged polyelectrolytes in poor solvents is studied in the weak segregation limit within the framework of the mean field approximation using a method first developed by Leibler. As a result a complete phase diagram of the solution near the c
Phase separation in polyelectrolyte solutions. Theory of complex coacervation
β Scribed by Overbeek, J. T. G. ;Voorn, M. J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1957
- Tongue
- English
- Weight
- 881 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0095-9898
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The excess Helmholtz free energy AF of rodlike and wormlike polyelectrolyte solutions over that of solvent is formulated from a perturbation theory, where the hard core and electrostatic potentials between two polymers are taken as the pair potentials of the reference system and the perturbation, re
## Abstract Formation of insoluble polyelectrolyte complexes (PECs) between RNA and polycations was followed by measuring the residual RNA absorbance in the solution after separation of the precipitate. The polycations studied were poly(__N__,__Nβ²__βdimethyldiallylammonium) chloride (pendant type)