Phase separation conditions for solutions of styrene copolymer with elastomer in a mixture of two monomers
โ Scribed by S.S. Karaenev; M.K. Chilingirjan
- Book ID
- 107753944
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 146 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0014-3057
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## Abstract **Summary:** A model system, consisting of a linear polymer dissolved in a bifunctional monomer/coโmonomer solvent, was selected to test the applicability of the FloryโHuggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers.
A method is presented which allows the calculation of phase diagrams (spinodal, binodal and tie lines) on the basis of the Gibbs energy of mixing AG. No derivatives of AG with respect to the composition variables are required. This method is particularly useful in cases where the composition depende