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Phase equilibrium of polydispersed polymer solution and fractionation

✍ Scribed by Okamoto, H. ;Sekikawa, K.

Book ID
104531985
Publisher
John Wiley and Sons
Year
1961
Weight
532 KB
Volume
55
Category
Article
ISSN
0022-3832

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✦ Synopsis

Abstract

Phase equilirium of a polydispersed polymer solution was investigated. Experiments on the system of linear polyethylene, xylene, and ethylene glycol were found to be approximately described by Flory's theory. To obtain a more precise description, the authors give a modification of Flory's relation. Methods by which the molecular size distribution of the fractionated polymer can be calculated from that of the unfractionated are proposed. Conditions favorable to effective fractionation are also briefly discussed.

πŸ“œ SIMILAR VOLUMES

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✍ Naveen Koak; Robert A. Heidemann πŸ“‚ Article πŸ“… 2001 πŸ› American Institute of Chemical Engineers 🌐 English βš– 122 KB πŸ‘ 2 views

## Abstract A technique is described for performing phase boundary calculations (cloud‐point calculations) for solutions of a polydisperse polymer in a solvent component. The polymer is characterized as a potentially large number of individual components. The technique employs the Newton method for

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