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Phase equilibria in the HgSe–HgBr2–HgI2 system and crystal structure of Hg3Se2Br2 and Hg3Se2I2

✍ Scribed by Yu.V. Minets; Yu.V. Voroshilov; V.V. Pan’ko; V.A. Khudolii

Book ID
117622198
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
175 KB
Volume
365
Category
Article
ISSN
0925-8388

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Synthesis and Crystal Structure of Hg3S2I2 and Hg3Se2I2, New Members of the Hg3E2X2 Family
✍ Johannes Beck; Sylvia Hedderich 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 207 KB

The reactions of HgS and HgSe with HgI 2 yield Hg 3 S 2 I 2 and Hg 3 Se 2 I 2 , respectively. Orange crystals of Hg 3 S 2 I 2 and light red crystals of Hg 3 Se 2 I 2 are formed in evacuated glass ampoules at 2603C in yields of 50% as the only crystalline compounds. The crystal structures have been s