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pH-Responsive Supramolecular Nanovalves Based on Cucurbit[6]uril Pseudorotaxanes

✍ Scribed by Sarah Angelos; Ying-Wei Yang; Kaushik Patel; J. Fraser Stoddart; Jeffrey I. Zink

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
696 KB
Volume
47
Category
Article
ISSN
0044-8249

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20 times more rapid is the complexation of the organic ammonium ion receptor cucurbit[6]uril (CB6) with cyclohexylmethylamine than with the cyclohexylmethylammonium species. Within the narrow pH region around the pK value of the amine, the complexation kinetics are accelerated but the binding consta