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pH influence on the complexation site of Al(III) with protocatechuic acid. A spectroscopic and theoretical approach

✍ Scribed by Cornard, Jean-Paul; Lapouge, Christine; André, Erwan

Book ID: 120420665
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 1010 KB
Volume: 108
Category: Article
ISSN: 1386-1425
DOI: 10.1016/j.saa.2013.02.005

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (