Rate constants for several reactions of inorganic radicals with inorganic anions in aqueous and aqueousiacetonitrile solutions have been measured as a function of temperature by laser flash photolysis. The reactions studied were (1) C12'-+ N3-, (2) Br2'-+ N3-, (3) C12'-+ SCN-, (4) Br2'-+ SCN-, (5) S
pH dependence of rate constants for reactions of cytochrome c with inorganic redox partners and mechanistic implications
โ Scribed by Drake, P. L.; Hartshorn, R. T.; McGinnis, J.; Sykes, A. G.
- Book ID
- 121346390
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 738 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0020-1669
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Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, COa'-, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80ยฐC. The reactants include the substitution-inert cyano complexes of Fe", Mo", and W"
## Abstract The fast flow method with laser induced fluorescence detection of CH~3~C(O)CH~2~ was employed to obtain the rate constant of __k__~1~ (298 K) = (1.83 ยฑ 0.12 (1ฯ)) ร 10^10^ cm^3^ mol^โ1^ s^โ1^ for the reaction CH~3~C(O)CH~2~โ+โHBr โ CH~3~C(O)CH~3~โ+โBr (1, โ1). The observed reduced react
## Abstract The recombination reactions of prototypical alkyl radicals (R) with O~2~, R + O~2~ โ RO~2~, have been investigated theoretically by using the variational transition state theory and RiceโRamspergerโKasselโMarcus theory/master equation calculations based on the CASPT2(7,5)/augโccโpVDZ//B